On-line isotope separation at the hilac

Isotope Effects, Isotope Separation and Isotope Fractionation

Electrochemical isotope effect and lithium isotope separation.

A large electrochemical isotopic effect is observed upon the electrodeposition of lithium from solutions of propylene carbonate producing isotopically light metal deposits. The magnitude of fractionation is controlled by the applied overpotential and is largest close to equilibrium. Calculated partition function ratios for tetrahedrally coordinated lithium complexes and metallic lithium predict...

Laser isotope separation of uranium

A research effort was carried out at the Bhabha Atomic Research Centre (BARC), Mumbai, for developing laser-based techniques for enrichment of natural uranium to reactor-grade (2.5% to 3.0% U), with the potential to be economically scalable to industrial production. Three approaches – two molecular, namely CO2 laser-based approach and UF6-based approach, and one atomic, namely Atomic Vapour Las...

Molten Salts and Isotope Separation

The work on molten salts and isotope separation performed over the years at Université Pierre et Marie Curie and at Collège de France is critically reviewed. This research, closely related to A. Klemm’s pioneering contributions, leads among other things to the discovery of the effect now called the ‘Chemla effect’, after the late Professor Marius Chemla. These studies of ionic motions in melts,...

On-line blind equalization via on-line blind separation

A blind equalization method based on the theory of independent component analysis is presented. The blind equalization of an unknown FIR channel with possibly non-minimum phase is formulated as a blind separation problem. The inputs to the equalizer are formed by stacking the fractional samples of the channel outputs. New on-line blind equalization algorithms are developed from on-line blind se...